摘要
详细阐述了Cu基催化剂的研究进展,重点从催化剂的反应机理、构效关系和活性位点进行了讨论。此外还概述了贵金属催化剂、In_(2)O_(3)基催化剂和其他新型催化剂的最新进展,以增强当前对CO_(2)加氢制甲醇的理解。最后,对现有催化剂存在的问题进行了分析,并提出了今后可能的研究方向。
In this review,the research progress on Cu-based catalysts is described in detail,focusing on the reaction mechanism,structure-activity relationship and active site of the catalysts.Furthermore,latest research advances on noble metal catalysts,In_(2)O_(3)-based catalysts and other novel catalysts are summarized to enhance current understanding to the hydrogenation of carbon dioxide to methanol.Finally,the problems for the existing catalysts are analyzed,and the possible research directions in the future are proposed.
作者
林代峰
张臻
罗永晋
钱庆荣
陈庆华
LIN Dai-feng;ZHANG Zhen;LUO Yong-jin;QIAN Qing-rong;CHEN Qing-hua(College of Environmental Science and Engineering,Fujian Normal University,Fuzhou 350007,China)
出处
《现代化工》
CAS
CSCD
北大核心
2021年第6期11-16,共6页
Modern Chemical Industry
基金
国家重点研究计划“固废资源化”重点专项(2019YFC1904500)
国家自然科学基金项目(21875037)。
关键词
二氧化碳加氢
甲醇
催化剂
反应机理
构效关系
hydrogenation of carbon dioxide
methanol
catalysts
reaction mechanism
structure-activity relationship