铀催化的氮气活化

Dinitrogen Activation by Uranium Complex

氮气约占空气总体积的78%,是大自然赋予人类的宝贵资源。如何实现氮气转化为动植物可利用的含氮化合物,关系着人类的未来和社会的可持续发展。氮气活化,作为一个非常重要的研究领域,一直以来都是科学家面临的重大挑战。目前,低价铀金属有机化合物展现出良好的小分子活化能力。本综述主要介绍了含铀化合物对氮气活化的研究进展,并对其未来进行了展望。

Dinitrogen is the most abundant gas in the air(approximately 78%of the total air volume),which is a precious resource endowed by nature.How to make use of dinitrogen and transform it into useful nitrogenous compounds is important for humans and sustainable development of society.Dinitrogen activation,as a very important research field,has always been a major challenge.At present,low valent uranium complexes exhibit excellent performance in the small molecule activation.This review mainly introduces and summarizes the application of uranium complexes in dinitrogen activation and transformation,and the prospect of this field is prognosticated.