摘要
High-rate anode materials for lithium-ion batteries are desirable for applications that require high power density.We demonstrate the advantageous rate capability of few-layered graphene nanosheets,with widths of 100-200 nm,over micro-scale graphene nanosheets.Possible reasons for the better performance of the former include their smaller size and better conductivity than the latter.Combination of SnO_(2)nanoparticles with graphene was used to further improve the gravimetric capacities of the electrode at high charge-discharge rates.Furthermore,the volumetric capacity of the composites was substantially enhanced compared to pristine graphene due to the higher density of the composites.
基金
The authors gratefully acknowledge the National Natural Science Foundation of China(Nos.90206048 and 20371004)
the Ministry of Science and Technology of China(Grant Nos.2006CB932701 and 2007AA03Z311)for financial support.