摘要
Breaking the space-time symmetries in materials can markedly influence their electronic and optical properties.In 3R-stacked transition metal dichalcogenides,the explicitly broken inversion symmetry enables valley-contrasting Berry curvature and quantization of electronic angular momentum,providing an unprecedented platform for valleytronics.Here,we study the valley coherence of 3R WS_(2) large single-crystal with thicknesses ranging from monolayer to octalayer at room temperature.Our measurements demonstrate that both A and B excitons possess robust and thickness-independent valley coherence.The valley coherence of direct A(B)excitons can reach 0.742(0.653)with excitation conditions on resonance with it.Such giant and thickness-independent valley coherence of large single-crystal 3R WS_(2) at room temperature would provide a firm foundation for quantum manipulation of the valley degree of freedom and practical application of valleytronics.
基金
This work was supported financially by the NSFC(grants:11834017 and 61888102)
the Strategic Priority Research Program of CAS(grant:XDB30000000)
the Key Research Program of Frontier Sciences of CAS(grant:QYZDBSSW-SLH004)
the National Key R&D program(grant:2016YFA0300904)
the financial supports from Business Finland(A-Photonics)
the Academy of Finland(grants:276376,284548,286920,295777,298297,304666,312297,312551,and 314810)
the Academy of Finland Flagship Programme(320167,PREIN)
the European Union’s Horizon 2020 research and innovation programme(820423,S2QUIP).