摘要
Multiferroics in which giant ferroelectric polarization and magnetism coexist are of tremendous potential for engineering disruptive applications in information storage and energy conversion.Yet the functional properties of multiferroics are thought to be affected detrimentally by the presence of point defects,which may be abundant due to the volatile nature of some constituent atoms and the high temperatures involved in the synthesis of materials.Here,we demonstrate with theoretical methods that oxygen vacancies may enhance the functionality of multiferroics by radically changing their magnetic interactions in thin films.Specifically,oxygen vacancies may restore missing magnetic super-exchange interactions in large axial ratio phases,leading to full antiferromagnetic spin ordering,and induce the stabilization of ferrimagnetic states with considerable net magnetizations.Our theoretical study should help to clarify the origins of long-standing controversies in bismuth ferrite and improve the design of technological applications based on multiferroics.
