摘要
A novel white emitting organic diode has been simply realized by inserting a doped hole-blocking layer between the hole transporting layer(HTL)and the electron transporting layer(ETL).The structure of this device is ITO/CuPc/NPB/blocking layer:rubrene/Alq/MgAg.Copper phthalocyanine(CuPc)was used as a buffer layer,N,N'-bis-(1-naphthy1)-N,N'-DIPHENYL-1'-biphenyl-4,4'-diamine(NPB)as te HTL,and trimer of complex(Alq) as ETL.Indium tin oxide and MgAg were the anode and cathode,respectively.The emission spectrum of this device covers a wide range of visible region and can be sensitively adjusted by the concentration of rebrene.The white emission with the CIE(Commission International de l'Eclairage)color coordinates x=0.31,y=0.32,a maximum luminance of 8635 cd/m2,and the luminous efficiency 1.39lm/W at the luminance of 100 cd/m2 were obtained in the device with 1.5% rebrene concentration in TPBi.
基金
Supported by the National Natural Science Foundation of China under Grant Nos.59790050 and 69687002,and Shanghai Education Committee.