摘要
The rare-earth ions(Yb^(3+),Tm^(3+))and Li^(+),Bi^(3+)ions doped GdCa_(4)O(BO_(3))_(3) crystals were grown using the Czochralski pulling method.The second-harmonic-generation conversion efficiencies of the GdCOB:Yb and GdCOB:Tm crystals are 31.3%and 33.3%,respectively,while the undoped GdCOB crystal is 27.9%.The conversion efficiencies of Yb^(3+),Tm^(3+)doped GdCOB are improved by 12%and 19%,respectively,compared to that of the undoped one.The conversion efficiencies of Li^(+),Bi^(3+)doped GdCOB crystals are 33%and 38.3%,which are improved by 15%and 37%as compared to that of the undoped crystal.The results are discussed using the anion group theory.
基金
Supported by the National Natural Science Foundation of China under Grant No.69890235
the Research Fund for the Doctoral Program of Higher Education of China.