摘要
Mass transfer at hydrogen evolving mercury electrode has been studied by determining mass transfer coefficients of indicator ions as the function of current density of hydrogen evolution for various kinds of indica tor ions in sulphuric acid solution.Mercury adhering to metal substrates of Ni,Cu or Ag is used as mercury electrode to overcome its trembling during the electrolysis.The effect of difTerent indicator ions,electrode character istic,substrate material,diameter of electrode and temperature is examined.It is found that the transfer coefficient is proportional to the mass square root of current density of hydrogen evolution.
基金
supported by the Foundation of the State Education Commission for doctoral students
