摘要
生态皮革的制造已经逐渐成为传统皮革行业的未来之路,无铬鞣剂的开发能够从源头上避免铬资源的减少、含铬废弃物的污染等问题,同时可以解决潜在Cr^(6+)的致癌毒性,已经成为了行业的当务之急。本文根据无铬鞣剂的基本结构特点,对金属无铬鞣剂、有机无铬鞣剂还有有机-金属结合鞣剂的鞣制特点,及其与皮胶原纤维的结合原理进行归纳汇总与分析,并且综述了各类无铬鞣剂的研究进展,最后对其进一步的研究与发展方向进行了展望。本文系统综述了无铬鞣剂的研究现状和发展趋势,对无铬鞣剂的研究和开发有一定的指导参考意义。
Ecological leather manufacturing has gradually become the future of the traditional leather industry.The development of chromium-free tanning agents can avoid the reduction of chromium resources,the pollution of chromium-containing wastes and the potential carcinogenic toxicity of Cr^(6+) from the source,which is the primary goal of the industry.Based on the basic structural characteristics of chrome-free tanning agents,the tanning characteristics of chrome-free metal tanning agents,chrome-free organic tanning agents,chrome-free organic-metal combination tanning agent and the principles of their combination with skin collagen fibers were summarized and analyzed.Then the research status of various chrome-free tanning agents was reviewed.Finally,its further research and development direction were prospected.The research status and development trend of non-chrome tanning agents were systematically reviewed,which has certain guiding and reference significance for the research and development of non-chrome tanning agents.
作者
薛思怡
王学川
杨金
刘新华
孙思薇
马建标
谈正南
XUE Siyi;WANG Xuechuan;YANG Jin;LIU Xinhua;SUN Siwei;MA Jianbiao;TAN Zhengnan(College of Bioresources Chemical and Material Engineering,Shaanxi University of Science and Technology,Xi’an 710021,China;Institute of Biomass Functional Materials,Shaanxi University of Science and Technology,Xi’an 710021,China;Zhejiang Zhonghui Leather Technology Co.,Ltd,Chongfu 314511,China)
出处
《中国皮革》
CAS
2021年第8期94-99,共6页
China Leather
基金
国家自然科学基金项目(22078183)
科技部“十三五”国家重点研发计划专项(2017YFB0308500)。
关键词
无铬鞣
金属无铬鞣剂
有机无铬鞣剂
有机-金属无铬鞣剂
生态皮革
chrome-free tanning
chrome-free metal tanning agent
chrome-free organic tanning agent
chromefree organic-metal combination tanning agent
ecological leather