摘要
以1,5-二氟-2,4-二硝基苯和3,4,5-三甲氧基甲苯为起始原料,经环化、甲基化、硝化和去甲基化反应,合成了一种新型杯芳烃衍生物,其结构经^(1)H NMR,^(13)C NMR和元素分析表征。
A novel calixarene derivatives was synthesized by cyclization,methylation,nitration,and demethylation reactions using 1,5-difluoro-2,4-dinitrobenzene and 3,4,5-trinitrotoluene as starting materials,The structure was characterized by ^(1)H NMR,^(13)C NMR,and elemental analysis.
作者
邹芳芳
张行程
张梦娇
胡文祥
ZOU Fang-fang;ZHANG Xing-cheng;ZHANG Meng-jiao;HU Wen-xiang(School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China;Green Catalysis & Synthesis Key Laboratory of Xinyang City, College of Chemistry and Chemical Engineering, XinYang Normal University, Xinyang 464000, China;Jingdong Xianghu Microwave Chemistry Union Laboratory, Beijing Shenjian Tianjun Academy of Medical Sciences, Beijing 101601, China;Aerospace Systems Division, Strategic Support Troops, Chinese People’s Liberation Army, Beijing 100101, China)
出处
《合成化学》
CAS
2021年第8期701-704,共4页
Chinese Journal of Synthetic Chemistry
基金
河南省科技攻关项目(182102310277)
河南省科技智库项目(HNKJZK-2020-34C)
河南省自然科学基金资助项目(202300410337)
信阳师范学院重大预研项目(20078,19162)。
关键词
耐热炸药
杯芳烃
含能材料
环化
硝化
合成
heat resistant explosive
calixarene
energetic material
cyclization
nitration
synthesis
