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环氧树脂辅助制备LiNi1/3Co1/3Mn1/3O2及其储锂性能

Preparation of LiNiCoMnO by the Assistant of Epoxy Resin and Its Lithium Storage Performance
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摘要 采用环氧树脂来均匀分散Li+,Co2+,Mn2+和Ni2+,并通过环氧树脂低温固化来维持离子均匀分散,续以空气中充分煅烧制备LiNi1/3Co1/3Mn1/3O2材料。电化学研究显示,850℃下制得的材料具有更好的充放电性能,0.2℃倍率下的首次充放电容量分别达到186.4和135.1mAh·g-1。 In this work,LiNi1/3Co1/3Mn1/3O2 is prepared by one-step method of calcinating the precursor at air atmosphere,which is obtained by solidifying epoxy resin solution containing Li+,Co2+,Mn2+ and Ni2+ ions in well mixing state.Electrochemical analysis show that the sample obtained at 850℃ displays an excellent charge/discharge performance,at 0.2 C the initial charge and discharge capacities can be 186.4 and 135.1 mAh ·g-1 respectively.
作者 王秀利 朱铮瑶 陈卓新 黄俊杰 Wang Xiuli;Zhu Zhengyao;Chen zhuoxin;Huang Junjie(Technical Center Wolong Electric Group Zhejiang Dengta Power Source Co.,Ltd.,Shaoxing 312000;College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030000;College of Chemistry and Chemical Engineering,Shaoxing University,Shaoxing 312000,China)
出处 《广东化工》 CAS 2021年第13期29-30,共2页 Guangdong Chemical Industry
关键词 LINI1/3CO1/3MN1/3O2 环氧树脂 正极材料 锂离子电池 LiMn0.33Ni0.33Co0.33O2 epoxy resin cathode lithium ion battery
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