IRMOFs基金属有机骨架材料合成及性能优化研究进展

Research progress on synthesis and performance optimization of isoreticular metal-organic frameworks(IRMOFs)

金属有机框架材料(MOFs)因其具有结构多样、孔隙率高、孔径可调等优点而展现出在催化、能量转化、气体储存和环境修复领域的巨大应用潜力。网状金属-有机骨架材料(IRMOFs)作为其中的主要类别材料,具有比表面积大、孔隙率高、调节孔径简单和价格低廉等特点,使其区别于其他MOFs材料,成为在气体吸附、催化、荧光等领域具有巨大应用潜力的优质材料。综述近年来IRMOFs系列材料发展、合成和性能优化的设计原理和策略,为在这个领域获得更高性能的复合材料提供研究参考,同时指出IRMOFs系列材料的研究前景和挑战。

In recent years,mental-organic frameworks(MOFs)have shown great potential for applications in catalysis,energy transformation,gas storage and environmental remediation due to their multiplicate structures,high porosity,and adjustable pore size.Isoreticular metal-organic frameworks(IRMOFs)as the main category of materials,have the characteristics of large specific surface area,high porosity,simple pore size adjustment,and low price,making it different from other MOFs materials.In the field of gas adsorption,catalysis,fluorescence and other fields,IRMOFs were high-quality materials with great application potential.This article reviews the development of IRMOFs series materials in recent years,the synthesis of materials and the design principles and strategies for optimizing material properties.It provides research ideas for obtaining high-performance composite materials in each field and points out the research prospects and challenges of IRMOFs series materials.