Charge transfer and excitation processes in low energy collisions of He ions with Li atoms

Electron capture between solar wind ions and neutral species has contributed to the understanding of X-ray production from solar system bodies.The charge transfer and excitation processes in solar wind ions of He^(+)(1 s) colliding with Li(1 s^(2)2 s) atoms are studied by utilizing the full quantum-mechanical molecular-orbital close-coupling(QMOCC) method with impact energies of 0.003-2 keV amu-1.Comparisons of cross sections from single-and multi-configurational calculations for a selfconsistent field(SCF and MCSCF) process are carried out.Results show that the dominant reaction channels are He(1 s2 l ^(1,3) L)+Li^(+)(1 s^(2) ^(1) S).Good consistency is found among present total and state-selective charge transfer and excitation cross sections with other theoretical and experimental data in the same energy region.Due to the differences between coupling matrix elements in high-energy states,the charge transfer cross sections calculated from SCF and MCSCF split slightly as E> 0.4 keV amu-1.Weak Stueckelberg oscillations for charge transfer appear in the present work.In addition,the differences of cross sections for electron excitation to Li(ls^(2)2 p) in the singlet/triplet molecular states with He+(1 s) are much smaller than those of charge transfer processes because of the similar energy gaps from Li(ls^(2)2 p) to the ground state in singlet/triplet states in the large R region.