摘要
The serendipitous discovery of dumb-bell-shaped C_(120) under high-speed vibration milling conditions is described.The mechanochemical protocol has been employed to synthesize the He-,H_(2)-or H_(2)O-encapsualted C_(120),the cross-dimer C_(130),trimer C_(180),bridged C_(60) dimers as well as products from many other reactions of fullerenes,carbon nanotubes and graphenes.Mechanochemistry extended to various reactions of non-fullerene molecules is briefly discussed.
基金
The continuous financial support from the Chinese Academy of Sciences and National Science Foundation of China(Nos.20125205,20772117,21132007,21372211)for our mechanochemistry study is acknowledged.
