硫代磷(膦)酸酯的合成研究进展

Advances in the Synthesis of Phosphorothioate and Phosphinothioate

硫代磷(膦)酸酯在农药、医药以及有机合成等研究领域具有广泛应用.重点总结了由P(O)-H化合物出发合成硫代磷(膦)酸酯类化合物的研究方法,按硫元素的不同来源分类,对该类反应的研究进展进行综述.

Organophosphorus compounds which contain phosphorus-sulfur bonds have been widely used in the fields of pesticides,pharmaceuticals and organic synthesis.The recent progress of the methods for the synthesis of phosphorothioate and phosphinothioate from P(O)—H reagents are summarized on the basis of different types of sulfur source.