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Electrospinning Janus Type CoO_(x)/C Nanofibers as Electrocatalysts for Oxygen Reduction Reaction 被引量:5

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摘要 Nanofibers with unique structures and multiple components have attracted more and more attention,which could combine multi-functions in one entity.Janus-type biphasic nanofibers with unique structure can be quickly obtained by electrospinning technology.We produced CoO_(x)/C nanofibers with Janus structure by self-made side-by-side electrospinning spinneret,combined with electrospinning technology and heat treatment.CoO_(x)/C nanofibers had a large amount of graphitic carbon distributed on one half of the Janus nanofiber,and CoO_(x)/C nanoparticles were embedded in the other half of the Janus nanofiber and distributed uniformly.CoO_(x)/C acted as ORR catalysis,and graphitic carbon,pridinc-N and CoO_(x) in CoO_(x)/C had a synergistic effect on their catalytic activity.The results confirmed that CoO_(x)/C was dominated by four-electron pathway under alkaline conditions,and the Tafel slope was lower than that of commercial Pt/C catalysts.The preparation method of this work is simple and easy,the structure is controllable,and the composition is adjustable,which provides a feasible way for preparing Janus structure nanofibers with different functions.
出处 《Advanced Fiber Materials》 CAS 2020年第2期85-92,共8页 先进纤维材料(英文)
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