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金属流化床电沉积研究(Ⅰ) 被引量:1

Electrodeposition of Metals in Fluidized Bed
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摘要 用流化床电沉积设备处理酸性含铜废水,在适当操作条件下,效率高,能耗低,治理污染和回收金属都取得令人满意的结果。(一)实验装置流化床电沉积设备的实验装置如图1所示。电解槽为高1米内径0.15米的有机玻璃管,铜粒阴极、钛钌阳极与多孔塑料隔膜松成。 A fludized cathode was employed to treat waste water containg copper in which the electrodeposit copper concentration were in 0-5kg/m^(3) range and the waste water was acidified to pH≤1.5.Superficial current densities were 280A/m^(2),while the copper was deposited about 0.12 kg per hour.Current efficiency could be over 93%,and power consumption per kilogram of copper deposited was 2.7-3.0 kW·h.It has both benefit public and economic.
作者 阎桂蕃 赫修德 张蕴壁 Yan Guifan;He Xiude;Zhang Yunbi(Chemical Engineering Department,Northwestern University,Xi'an)
机构地区 西北大学化工系
出处 《高等学校化学学报》 SCIE EI CAS 1987年第11期1039-1040,共2页 Chemical Journal of Chinese Universities
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  • 1Hutin D, Coeuret F. Experimental study of copper deposition in a fluidized bed electrode [J]. J Appl Electrochem, 1977, 7(6):463-471.
  • 2Goodridge F, Vance C J. Copper deposition in a pilot-plant-scale fluidized bed cell [J]. Electrochimica Acta, 1979, 24(12):1237-1242.
  • 3Huh T, Evans J W , Carey C D. The fluidized bed electrowinning of silver [J]. Metallurgical Transaction B, 1983, 14B(3): 353-357.
  • 4Jircny V, Evans J W. Fluidized-Bed electrodeposition of zinc [J]. Metallurgical Transactions B, 1984, 15B(4): 623-631.
  • 5YOU Cai-zhen (尤彩真), LING Qiu-qi (林秋其), XUE Jian-jun (薛建军). Fluidized bed electrode processing copper platingwastewater (采用流态化床电极处理镀铜废水) [J].环境科学, 1981, 4(4): 27-29.
  • 6YUAN Quan (袁权), YANG Bo (杨波). Fluidized bed electrode (流化床电极) [J]. 化工进展, 1986(3): 6-10.
  • 7ZHOU Han-xing (周汉兴). Recovery of copper from dilute solution with fluidized bed electrode (采用流态化床电极从稀溶液中回收铜) [J]. 无机盐工业, 1985(2): 27-30.
  • 8YANGui-fan (阎桂藩), HE Xiu-de (赫修德), ZHANG Yun-bi (张蕴璧). Fluidization electrodeposition of industrial copperwastewater (工业含铜废水的流态化电沉积) [J]. 化工环保, 1988, 8(2): 85-87.
  • 9XU Wen-lin (许文林), WANG Ya-qiong (王雅琼), SUN Yan-ping (孙彦平). The recovery of silver from a copper electrolyte by afluidized-bed electrochemical reactor (流化床电化学反应器回收铜电解液中的银.化工冶金) [J]. Chemical Metallurgical, 1995,16(1): 77-80.
  • 10Morooka S, Kusakabe K, Watari T, et al. Effective specific resistance of a particle phase in a fluidized-bed electrode [J].International Chemical Engineering, 1981, 21(3): 465-472.

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