摘要
利用等摩尔竞争法我们研究了五种芳基三甲基硅烷与氯化氢的非均相断裂反应。用气体色谱法对各竞争反应产物进行定量分析,求出各断裂产物的相对性产率,结果表明其活性顺序是与相应的均相断裂反应相一致的。
By means of equimolecular competing reaction we investigated the cleavage of five aryl trimethyl silanes by hydrogen chloride.The cleavage products were quantitatively analyzed by gas cbromato-graphy.The selective yield of every cleavage product showed that the reactive sequance was in accordance with the result of corresponding homogeneous cleavage.
作者
周秀中
张增佑
梁格
郭聪元
磨强中
谢庆兰
徐善生
Zhou Xiuzhong;Zhang Zengyou;Liang Ge;Guo Congyuan;Me Qiangzhong;Xie Qinglan;Xu Shansheng(The Institute of Elemento-Oryanic Chemistry,Department of Chemistry,Nankai University,Tianjin)
出处
《高等学校化学学报》
SCIE
EI
CAS
1981年第2期195-200,共6页
Chemical Journal of Chinese Universities
