稀土乙酰丙酮-α,β,γ,δ-四邻硝基苯基卟啉钬的合成

SYNTHESIS OF ACETYLACETONATE-α,β,γ,δ- TETRA-O-NITROPHENYL PORPHYRIN HOLMIUM

本文首次合成出镧系乙酰丙酮-α,β,γ,δ-四邻硝基苯基卟啉配合物Ho(o-NO2)TPPacac(Ⅰ),并简单地讨论了它的性质。 反应中间物三水乙酰丙酮配合物Ho(acac)3·3H2O用文献方法[1]合成和纯制。α,β,γ,δ-四邻硝基苯基卟啉(o-NO2)TPP用改进的Kim,J.B.法[2]

This is a preliminary report on the preparation and characterization of lanthanide acetylacetonate-α,β,γ,δ-tetra-ο-nitrophenyl porphyrin complex: Ho(ο-NO_(2)-)TPPacac.