含硫希夫碱配合物的研究(Ⅰ)——S-甲基-β-N-(o-羟苯基乙叉)-二硫代肼基甲酸盐与镍和铜的配合物

Studies of Complexes of Schiff Bases Containing Sulfur (Ⅰ)——S-Methyl-β-N- (o-hydroxyphenylethylidene) -Dithiocarbazate Complexes with Nickel and Copper

以S-甲基-β-N-(o-羟苯基乙叉)-二硫代肼基甲酸盐为配体,分别合成了镍和铜的配合物,测定了它们的化学组成、配位比、红外光谱、溶液的电导和配合物的稳定常数,初步提出了配合物的结构。

The coordination compounds of nickel and copper with S-methyl-β-N-(o-hydroxyphenylethylidenc)-dithiocarbazate have been synthesized and characterized by elemental analysis, molar conductance and IR spectroscopic measurement. Theyhave the composition of Ni_(2)L_(2) and Cu_(2)L_(2) and the formation constants are 2.9×10^(12) and 4.7×10^(15) respectively.