N,N′-乙二水杨酰胺合铜(Ⅱ)酸根的Cu(Ⅱ)-Co(Ⅱ)配合物的合成与磁性

Synthesis and Magnetism of Copper(Ⅱ)-Cobalt(Ⅱ)Complexes with N,N’-Ethylenedisalicylamidatocuprate(Ⅱ)

本文报道了2个新的Cu(Ⅱ)-Co(Ⅱ)双核配合物的制备。经元素分析和红外、电子光谱以及变温磁化率的测定,研究了配合物的某些性质。

New binuclear complexes of type[Cu(samen)Co(L)]2 were synthesized,where samen4-denotes N,N’-ethylenedisalicylamidate anion and L denotes 2,2’-dipyridyl or 1,10-phenanthrolirie.Based on IR,elemental analyses and electronic spectra,the complexes are proposed to consist of aCu(Ⅱ)in a distorted planar environment and Cod in a distorted octahedron.The magnetisms of the Cu(Ⅱ)-Co(Ⅱ)complexes were well interpreted in terms of the susceptibility equation based on Heisenberg model.