摘要
本工作利用CuCl/HOC_(2)H_(4)NH_(2)催化剂,将1,2-二溴四氟乙烷与烯基有机硅化合物进行加威反应,制备了一系列新的含氟有机硅化合物,并进行了分析鉴定。对影响反应的诸因素做了初步探讨。
CuCl/HOC_(2)H_(4)NH_(2) catalystic system is used for catalysis of the addition of 1,2-dibromotetrafluoroethane to organosilicon compounds containing vinyl group.Aseries of unreported organosilicon compounds containing fluorine have been synthesized.The structures of the compounds synthesized have been determinated by elemental analysis and spectroscopic methods(^(1)H NMR and IR).Factors of affection on the reaction are investigated.
作者
杜作栋
陈剑华
张承智
Du Zuodong;Chen Jianhua;Zhang Chengzhi(Department of Chemistry,Shandong University,Jinan)
出处
《高等学校化学学报》
SCIE
EI
CAS
1987年第4期372-376,共5页
Chemical Journal of Chinese Universities
