两个新的氮杂环基氢硼酸根及其金属配合物的研究

Studies on Two N-Heterocyclic Hydroborates and Their Complexes

以硼氢化钾、咪唑、苯并三唑为原料,合成了一氢三(1-咪唑基)硼酸钾和二氢双(1-苯并三唑基)硼酸钾,并以它们为配体合成了一些金属配合物。

Two novel ligands,potassium monohydrotris(1-imidazolyl)borate and potassium dihydrobis(l-bcnzotriazolyl)borate have been synthesized via the molten reactions of potassium borohydride with imidazole or benzotriazole,these have been identified by MS,1HNMR,elemental analysis and IRspectra.Their complexes with Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),and Zn(Ⅱ)were described.