胺烷基二茂铁衍生物研究(Ⅱ)——(N、N-二乙基)胺甲基二茂铁钯配合物与烯烃的反应

Studies on Aminoalkylferrocene Derivatives (Ⅱ)--The Reactions for Palladium complex of N,N- Diefhylaminomethylferrocene with Olefins

本文报道了(N,N-二乙基)胺甲基二茂铁钯配合物的合成及其与烯烃的反应,以及(N,N-二乙基)胺甲基二茂铁(Ⅰ)、钯配合物(Ⅱ)和反应产物的波谱性质。 1 实验 1.1 仪器 IR光谱用Shimadzu IR-450红外分光光度计测定,固体用KBr压片,液体用CsI涂片。Ⅰ和反应产物的~1H NMR谱用Varian EM-390核磁共振仪测定,氘代氯仿作溶剂;Ⅱ用Varian XL-200核磁共振仪测定;氘代二甲亚砜作溶剂。均以TMS作内标。

In this communication we report on the synthesis of the palladium complex of N,N-diethylaminomethylferrocene, di-μ-chloro-bis(2-(diethylaminometh-yl)ferrocenyl)dipalladium, and its reactions with styrene, methyl propenate, and 2-ferrocenylpfopene. The palladium complex and all the reaction products, which have been identified by elemental analyses, IR, 1H NMR spectra, are 1,2-disubsti-tuted ferrocene.