形貌可控有机多孔聚合物:合成、功能化和应用

Morphologically Controllable Organic Porous Polymers:Synthesis,Functionalization and Application

有机多孔聚合物具有高的比表面积、优异的化学稳定性和丰富的构建方法,在吸附、分离和多相催化等多个领域具有广阔的应用前景。材料的结构、形貌在很大程度上决定了材料性能。为拓展有机多孔聚合物在更多领域的应用,形貌可控的有机多孔聚合物逐渐成为新的研究方向。通过合理的结构设计和采用不同的化学修饰方法,可获得具有不同形貌与性能的有机多孔聚合物,它们在不同方面展现出较好的应用潜力。针对形貌可控有机多孔聚合物的国内外研究现状,综述了形貌可控有机多孔聚合物的合成策略、功能化方法和应用领域,并对其今后的发展趋势做出了展望。

Based on the high surface area,excellent chemical stability and various preparation methods,organic porous polymers have broad application prospects in many fields including adsorption,separation and heterogeneous catalysis.The structure and morphology of the materials determine material properties to a great degree.To expand the application of organic porous polymers in more fields,organic porous polymers with controllable morphology have gradually become a new research direction.Organic porous polymers with different morphologies and properties can be obtained with reasonable structural design and various chemical modification methods,which shows good application potential in different aspects.In this paper,the synthesis strategy,functionalization methods and application of morphologically controllable organic porous polymers are reviewed based on the research situation at home and abroad,and the future development trends are also put forward.