摘要
Semiconductor photocatalysis is a potential pathway to solve the problems of global energy shortage and environmental pollution.Black phosphorus(BP)has been widely used in the field of photocatalysis owing to its features of high hole mobility,adjustable bandgap,and wide optical absorption range.Nevertheless,pristine BP still exhibits unsatisfactory photocatalytic activity due to the low separation efficiency of photoinduced charge carriers.In recent years,the construction of heterostructured photocatalysts based on BP has become a research hotspot in photocatalysis with the remarkable improvement of photoexcited charge-separation efficiency.Herein,progress on the design,synthesis,properties,and applications of BP and its corresponding heterostructured photocatalysts is summarized.Furthermore,the photocatalytic applications of BP-based heterostructured photocatalysts in water splitting,pollutant degradation,carbon dioxide reduction,nitrogen fixation,bacterial disinfection,and organic synthesis are reviewed.Opportunities and challenges for the exploration of advanced BP-based heterostructured photocatalysts are presented.This review will promote the development and applications of BP-based heterostructured photocatalysts in energy conversion and environmental remediation.
基金
financially supported by the National Natural Science Foundation of China(21902051,21861130353,U1905214,21961142019,22032002,21761132002,and 21425309)
the Fundamental Research Funds for the Central Universities(ZQN-807)
the Natural Science Foundation of Fujian Province(2019J05090 and 2017J01014)
the Graphene Powder and Composite Research Center of Fujian Province(2017H2001)
the Scientific Research Funds of Huaqiao University(20171XD033)
the Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment of Fuzhou University(SKLPEE-KF201803)
the National Key Technologies R&D Program of China(2018YFA0209301)
the National Basic Research Program of China(2013CB632405)
the Chang Jiang Scholars Program of China(T2016147)
the 111 Project(D16008).
