期刊文献+

环状碳酸酯的绿色合成方法 被引量:3

Green Synthesis of Cyclic Carbonate
下载PDF
导出
摘要 环状碳酸酯是高价值化学品,市场需求高。文章介绍以二氧化碳和二元醇为原料,以聚离子液体材料为催化剂,在温和条件下成功合成出环状碳酸酯。反应具有原料成本低、无毒无害、原子利用率高、副产物少等优点,是绿色合成方法。 Cyclic carbonate is a high-value chemical with high market demand.In this paper,cyclic carbonate was successfully synthesized under mild conditions with carbon dioxide and diol as raw materials and polyionic liquid as catalyst.The reaction has the advantages of low raw material cost,non-toxic and harmless,high atomic utilization rate and less by-products.It is a green synthesis method.
作者 刘阳庆 韩粉女 许琦 LIU Yang-qing;HAN Fen-nv;XU Qi(Yancheng Institute of Technology,Yancheng 224051,China)
机构地区 盐城工学院
出处 《化工管理》 2021年第32期15-16,共2页 Chemical Engineering Management
关键词 环状碳酸酯 二氧化碳 二元醇 聚离子液体 cyclic carbonate carbon dioxide diol polyionic liquid
  • 相关文献

参考文献3

二级参考文献22

  • 1[1]CLEMENTS J H.Reactive applications of cyclic alkylene carbonates[J].Ind Eng Chem Res,2003,42(4):663-674.
  • 2[2]ANASTAS P T,LANKEY R L.Life cycle assessment and green chemistry:The yin and yang of industrial ecology[J].Green Chem,2000,2(6):289-295.
  • 3[3]DELLEDONNE D,RIVETTI F,ROMANO U.Developments in the production and application of dimethyl carbonate[J].Appl Catal A,2001,221(1-2):241-251.
  • 4[4]WANG H,WANG M,ZHAO N,WEI W,SUN Y.CaO-ZrO2 solid solution:A highly stable catalyst for the synthesis of dimethyl carbonate from propylene carbonate and methanol[J].Catal Lett,2005,105(3-4):253-257.
  • 5[8]VINCENZO C,ANGELO N,ANTONIO M,ANTONELLO F.Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts[J].Org lett,2002,4(15):1561-2563.
  • 6[9]LU X,ZHANG Y,LIANG B,LI XIAO,WANG H.Chemical fixation of carbon dioxide to cyclic carbonates under extremely mild conditions with highly active bifunctional catalysts[J].J Mol Catal A,2004,210(1-2):31-34.
  • 7[10]ZHAO X,ZHANG Y,WANG Y.Synthesis of propylene carbonate from urea and 1,2-propylene glycol over a zinc acetate catalyst[J].Ind Eng Chem Res,2004,43(15):4038-4042.
  • 8[11]LI Q,ZHANG W,ZHAO N,WEI W,SUN Y.Synthesis of cyclic carbonate from urea and diols overmetal oxides[J].Catal Today,2006,115(1-4):111-116.
  • 9[12]TOMISHIGE K,YASUDA H,YOSHIDA Y,NURUNNABI M,BAITAO L,KUNIMORI K.Catalytic performance and properties of ceria based catalysts for cyclic carbonate synthesis from glycol and carbon dioxide[J].Green Chem,2004,6(4):206-214.
  • 10[13]TOMISHIGE K,YASUDA H,YOSHIDA Y,NURUNNABI M,BAITAO L,KUNIMORI K.Novel route to propylene carbonate:Selective synthesis from propylene glycol and carbon dioxide[J].Catal Lett,2004,95(1-2):45-49.

共引文献10

同被引文献34

引证文献3

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部