非平面芳烃的碳氢活化研究进展

Research progress in C—H activation of nonplanar aromatic hydrocarbons

碳氢(C—H)活化反应作为现代分子拼接的重要手段,具有原子经济性高、合成路线简单等优点,因此通过C—H活化对非平面芳烃进行衍生,逐渐成为有机化学研究的热点之一。该文系统归纳了近年来典型的非平面芳烃——环仿、螺烯、碗烯、花烯和富勒烯的C—H键活化反应,并对未来潜在的研究方向进行展望,以期获得更多优秀的非平面碳基材料。

C—H activation reaction,as an important means of modern molecular splicing,has the advantages of high atom economy and simple synthesis route.Therefore,the derivatization of nonplanar aromatics through C—H activation has gradually become one of the hottest topics in molecular science.The C—H activation reactions for nonplanar aromatics,such as cyclophane,helicenes,corannulene,sumanene and fullerene in recent years are systematically summarized.And the research directions in the future is prospected in order to obtain more excellent nonplanar carbon-based materials.