摘要
This article explores the effects of doping ferroelectric materials MgTiO_(3) with different proportions on the properties of polyaniline(PANI).PANI/MgTiO_(3) composites were prepared by in-situ composite method.Fourier transform infrared spectroscopy(FTIR)and X-ray diffraction(XRD)were used to characterize the structure of the composites.Scanning electron microscope(SEM)was used to characterize the morphology of the composites.The thermal stability of the composites was investigated by thermogravimetry(TG)and derivative thermogravimetry(DTG).Electrochemical methods(cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS),and constant current charge-discharge test)were used to compare and analyze the electrochemical performance of the composites.TG-DTG analysis and electrochemical experiments all show that the thermal stability and electrochemical properties of the PANI/MgTiO_(3) composite with a mass ratio of 82/18(w/w)are the best.The results indicate that there is a synergistic effect between PANI and MgTiO_(3),which improves the performances of the PANI when the appropriate amount of MgTiO_(3) is added.
作者
JIN Yazhou
XING Weiwei
ZHAO Siyu
GU Xiaojie
CHI Liping
YUAN Meng
XU Fen
WANG Shaoxu
晋亚周;XING Weiwei;ZHAO Siyu;GU Xiaojie;CHI Liping;YUAN Meng;XU Fen;王韶旭(College of Materials Science and Engineering,Dalian Jiaotong University,Dalian 116028,China;Dalian Eco-environmental Affairs Service Center,Dalian 116028,China;Guangxi Key Laboratory of Information Materials(Guilin University of Electronic Technology),Guilin 541004,China;College of Environmental and Chemical Engineering,Dalian Jiaotong University,Dalian 116028,China)
基金
Funded by the Natural Science Foundation of Liaoning Province(No.20180550736)
Research Foundation of Educational Committee of Liaoning Province(No.JDL2019004)
Guangxi Key Laboratory of Information Materials(Guilin University of Electronic Technology)(No.191008-K)。