以四苯基乙烯模块构筑的配位聚合物在催化性能方面的研究进展

Research progress in Catalytic Properties of Coordination Polymers Constructed with Tetraphenylethylene Modules

基于四苯基乙烯的易于修饰、具有刚性结构等特点使其可以用作配体,同时配位聚合物具有组成与结构多样、比表面积大、孔道尺寸及表面化学性质可调节等优异性,综合两者特点总结了近年来以四苯基乙烯为模块构筑的配位聚合物在催化性能方面的研究进展,探讨四苯基乙烯配位聚合物结构与性能之间的关系,展望未来设计性能优越、符合绿色化学的催化剂将会是新兴的发展趋势。

Tetraphenylethylene can be used as ligand because of its easy modification and rigid structure.At the same time,the coordination polymer has the advantages of diverse composition and structure,large specific surface area,adjustable pore size and surface chemical properties,Based on the characteristics of the two,this paper summarizes the research progress in the catalytic properties of coordination polymers constructed with tetraphenylethylene as modules in recent years,discusses the relationship between the structure and properties of tetraphenylethylene coordination polymers,and looks forward to the emerging development trend of designing catalysts with superior performance and in line with green chemistry in the future.