化学燃料驱动的耗散超分子自组装研究进展

Research progress on the chemical fuel driven dissipative supramolecular self-assembly

自然界广泛利用能量耗散自组装过程来构筑处于非平衡态的有序组装结构,并实现与组装状态相关的特定功能.受此启发,通过小分子构筑基元在外部输入能量的驱动下进行耗散自组装可以获得具有自适应性、自复制等独特性能的超分子组装智能材料.综述了近年来发展的3类以化学燃料驱动的耗散超分子自组装体系的构筑策略,并展示了所获得的瞬时超分子组装材料的应用,最后对这一研究领域的挑战和机遇作一总结.

Naturally the energy-dissipating self-assembly process was widely used to construct ordered assembly structures in a non-equilibrium state,through which the specific chemical functions related to the assembled states could be achieved.The dissipative self-assembly systems featuring with unique self-adaptation and self-replication could be fabricated via the supramolecular self-assembly of small molecular building blocks driven by the energy consumption.It was reviewed and summarized the recent research progress on the construction strategies as well as the applications of dissipative supramolecular self-assembly systems driven by chemical fuels.It was also provided discussions on the challenges and outlooks in the relative research field.