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新型Michael加成反应催化剂研究进展 被引量:2

Research Progress in Catalysts for Michael Addition Reaction
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摘要 Michael加成反应是指烯醇盐负离子与α,β-不饱和化合物的共轭加成反应,是最重要的有机合成反应之一,Michael加成反应催化剂研究是化学研究的热点。综述了近十年来新型Michael加成反应催化剂如新型的有机小分子催化剂、负载催化剂及其他特殊催化方法等的研究进展,着重探讨了新型催化剂的高效性和催化剂再利用,同时指出,开发催化Michael加成反应的高效环境友好型催化剂是今后研究的重点。 Michael addition reaction,which is one of the best important organic synthesis reactions,is a conjugate addition reaction of enolate anion withα,β-unsaturated substances.The research progress of new type catalysts for Michael addition reaction in recent twenty years was reviewed,such as new organic catalysts,loading catalysts and other special catalytic methods.The catalytic efficiency and the catalyst reusing were discussed.Meanwhile,it was proposed that the development of the high efficiency and environment friendly catalysts for Michael addition reaction would be a key research focus in the future.
作者 柴凤兰 张帆 葛荣欣 白孟恩 CHAI Feng-lan;ZHANG Fan;GE Rong-xin;BAI Meng-en(Research Center for Applied Technology,Henan Technical Institute,Zhengzhou,450042,China;School of Chemistry and Chemical Engineering,Henan University of Technology,Zhengzhou,450001,China)
出处 《当代化工》 CAS 2021年第11期2702-2711,2716,共11页 Contemporary Chemical Industry
基金 河南省科技厅科技攻关项目,混合模式色谱固定相的合成、表征及在食品安全中应用研究(项目编号:152102310326) 河南省教育厅科技攻关项目,木醋液的制备和畜禽养殖用木醋液复合制剂的开发(项目编号:21B150007)。
关键词 MICHAEL加成反应 催化剂 选择性 活性 Michael addition reaction Catalysts Selectivity Reactivity
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