摘要
In this study,MgAl-V_(2) O_7^(4-) LDHs/(poly(ethyleneimine)(PEI)/MXene)_n composite films were synthesized via(ⅰ) in-situ hydrothermal growth of Mg-AL layered double hydroxides(LDHs) on AZ31 alloy followed by vanadate intercalation reactions,and(ⅱ) the as-prepared MgAL-V_(2) O7^(4-) LDHs film was covered by layerby-layer assembly using(PEI/MXene)_n,where n=5,10,and 20.Film characterization revealed that the outer layers(PEI/MXene) were assembled on the surface by electrostatic interaction and provided a good coverage of LDHs nanosheets.But,microcracks appeared gradually on the surface and destroyed the film integrity with increasing number of PEI/MXene layers.The corrosion tests indicated that the MgAl-V_(2) O_7^(4-)LDHs/(PEI/MXene)_(10) composite films provided a better corrosion protection ability than that of n=5 and20.The outer layers(PEI/MXene) had a corrosion inhibition protective effect on MgAl-V_(2) O_7^(4-) LDHs film.This work opened a new perspective of the MXene materials for anticorrosion application via a layer-bylayer assembly method.
基金
supported by the National Natural Science Foundation of China (51971040, 51971044)
the Fundamental Research Funds for the Central Universities (2020CDJQY-A007)。
