摘要
The development of sodium-ion(SIBs)and potassium-ion batteries(PIBs)has increased rapidly because of the abundant resources and cost-effectiveness of Na and K.Antimony(Sb)plays an important role in SIBs and PIBs because of its high theoretical capacity,proper working voltage,and low cost.However,Sb-based anodes have the drawbacks of large volume changes and weak charge transfer during the charge and discharge processes,thus leading to poor cycling and rapid capacity decay.To address such drawbacks,many strategies and a variety of Sb-based materials have been developed in recent years.This review systematically introduces the recent research progress of a variety of Sb-based anodes for SIBs and PIBs from the perspective of composition selection,preparation technologies,structural characteristics,and energy storage behaviors.Moreover,corresponding examples are presented to illustrate the advantages or disadvantages of these anodes.Finally,we summarize the challenges of the development of Sb-based materials for Na/K-ion batteries and propose potential research directions for their further development.
基金
financial support by the National Natural Science Foundation of China(Nos.51771130,51531004,and 51422104)
the Tianjin Youth Talent Support Program,the Tianjin Natural Science Funds for Distinguished Young(No.17JCJQJC44300)
the Tianjin Science and Technology Support Project(No.17ZXCLGX00060)
the China Postdoctoral Science Foundation(No.2020M670649)。
