电催化醇选择性氧化为醛酮的研究进展

Research Progress of Selective Oxidation of Alcohols to Aldehydes and Ketones by Electrocatalysis

醇选择性氧化为相应的羰基化合物是有机化学中最常用的生成羰基化合物的反应,电催化氧化具有反应条件温和、环境友好等优点,是一种非常有前途的醇催化氧化绿色生产工艺.我们综述了直接和间接电催化氧化反应的方法,并对各类体系的催化效果进行了简要介绍.

Selective oxidation of alcohols to corresponding carbonyl compounds is the most commonly used reaction in organic chemistry to generate carbonyl compounds.Electrocatalytic oxidation has the advantages of mild reaction conditions and environmental friendliness,which is a very promising green production process of alcohols catalytic oxidation.In this paper,the methods of direct and indirect electrocatalytic oxidation reactions are reviewed,and the catalytic effects of various systems are briefly introduced.