摘要
Perovskite solar cells(PSCs)are attracting much attention and are on the way to commercialization.However,some modules are subject to reverse bias in actual fields,so it is meaningful to investigate the reverse-bias behav-ior of PSCs.Herein,an in-situ temperature and current measurement technique was developed.Intriguingly,some hot spots were observed and then quickly disappeared in the reverse biased PSCs,along with the simultaneous increase in the current and local temperature.Also,the potential mechanism has been revealed and analyzed.An abnormal bulge in the perovskite film was found at the hot spot.Accordingly,the appearance and disappearance of hot spots were perfectly explained by band bending and tunneling current caused by ion accumulation.Addi-tionally,statistical analysis suggested that sparkling hot spots were related to reverse voltage and efficiencies of PSCs.The research provides a great significance for the study of PSCs under reverse bias.
基金
This work was supported by the National Natural Science Founda-tion of China(11875229,61505264 and 52173192)
the National Key Research and Development Program of China(2017YFA0206600)
the Science and Technology Innovation Program of Hunan Province(No.2020RC4004)
the Special Funding for the Construction of Innova-tive Provinces in Hunan Province(No.2020GK2024).
