摘要
Supported metal catalysts,in which the metal is usually finely dispersed into nanoparticles(NPs)in size of a few nanometers on high-surface-area materials,are the workhorses in heterogeneous catalysis and have been extensively used in various key industrial processes[1].However,the surface heterogeneity arising from the uneven size distribution as well as the lower atomic efficiency derived from the presence of unexposed interior atoms of metal NPs often leads to inferior activity/selectivity.