摘要
针对含钾岩石的综合利用,以KOH-KF为活化助剂,进行了亚熔盐法活化含钾岩石制备W沸石的研究。采用X射线衍射(XRD)确定了活化产物的组成。实验结果表明,适宜的活化条件为:KF和KOH量比n(KF)/n(KOH)为0.05,KOH和含钾岩石质量比m(KOH)/m(potassic ores)为3,KOH质量分数为70%,反应时间为6 h,反应温度为190℃。向上述适宜活化条件下获得的液固混合产物中按照一定比例补加KOH、气相SiO_(2)和H_(2)O,采用水热法合成了W沸石。制得的W沸石经钠改型后在模拟海水中的提钾量(K+)为48.39 mg×g^(-1)。合成沸石的母液经浓缩后被再次用于含钾岩石活化,有利于实现资源节约和工业化应用。
Potassic ores were activated by a sub-molten salt method using KOH-KF as the activating agent to prepare zeolite W.The composition of activated products was determined by X-ray diffraction(XRD).The experimental results show that the suitable activation conditions are n(KF)/n(KOH)=0.05,m(KOH)/m(potassic ores)=3,KOH mass fraction=70%,reaction time=6 h and reaction temperature=190℃.KOH,fumed silica and H_(2)O were added to the resulted liquid-solid mixture and zeolite W was synthesized by a hydrothermal method.The zeolite W modified by sodium exhibits potassium extraction capacity of 48.39 mg×g^(-1) from simulated seawater.The mother liquor of synthesized zeolite was concentrated and reused for the activation of potassic ores,which is helpful for energy conservation and industrial application.
作者
刘洋
张恕
李雲
曹吉林
LIU Yang;ZHANG Shu;LI Yun;CAO Ji-lin(Engineering Research Center of Seawater Utilization Technology of Ministry of Education,School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China)
出处
《高校化学工程学报》
EI
CAS
CSCD
北大核心
2022年第1期85-91,共7页
Journal of Chemical Engineering of Chinese Universities
基金
国家自然科学基金(22008049)
河北省自然科学基金(B2018202330,B2020202081)
中国科学院天然气水合物重点实验室(中国科学院广州能源研究所)资助(E029kf1601)。