摘要
Comprehensive Summary(±)-Atrachinenins A—C(1—3),three meroterpenoids possessing novel C_(27) skeletons,were isolated from the rhizomes of Atractylodes chinensis.(±)-Atrachinenin A(1)possesses an unprecedented cage-like skeleton with a fused 6/6/5/5 tetracyclic system(decahy-dro-1,5:4a,7-dimethanobenzo[7]annulene),which may be formed by the intermolecular cyclization of(±)-atrachinenin C(3).
基金
supported by Macao Science and Technology Development Funds(0008/2019/A,0075/2019/AGJ,and 0023/2019/AKP).