摘要
Two new 3-D Cd(Ⅱ) coordination polymers with p-phthalic acid (p-BDC) and 4,4′-dipyridylamine (4,4′-dpa),namely[Cd_(2)(p-BDC)_(2)(4,4′-dpa)_(2)]_(n) 1 and{[Cd(p-BDC)(4,4′-dpa)(H_(2)O)]·4H_(2)O}_(n) 2 were successfully synthesized under hydrothermal conditions at 120 and 140℃.They were characterized by single-crystal X-ray diffraction,IR,PXRD and TGA.It was further characterized by Hirshfeld surface (HS)analysis for complex 2.The luminescent properties of the complexes have also been investigated.
基金
supported by the Foundation of Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials (EMFM20161102)
the National Natural Science Foundation of China (No. 61765005)。
