摘要
In recent years,porphyrins with a similar structure to chlorophyll are often used as photosensitizers or reaction centers to improve the light absorption capacity or catalytic selectivity of existing photocatalytic systems.However,photocatalytic reactions include photoelectric conversion,photocarrier transport,and surface reaction,which requires the overall design of porphyrin-based photocatalysts.In this paper,the research work of porphyrin molecular design in heterogeneous photocatalysis in recent years is reviewed.Besides,the application of interface control and spatial confinement effect in porphyrin-based hybrid photocatalyst is introduced.Finally,the future development direction of porphyrin-based photocatalysts is prospected and the main challenges in the research of porphyrin-based photocatalysts are given.
基金
supported by the National Natural Science Foundation of China(Nos.51972345,51972342)
Taishan Scholar Project of Shandong Province(No.ts20190922)
Key Basic Research Project of Natural Science Foundation of Shandong Province(No.ZR2019ZD51)
Fundamental Research Funds for the Central Universities(No.19CX05001A)。
