摘要
The separation of carbon dioxide(CO_(2))is of great importance for environment protection and gas resource purification.The ionic liquids(ILs)-based gas separation membrane provides a new chance for efficient CO_(2)separation,while high permeability and selectivity of membranes is a great challenge.In this study,the influence of two protic ILs with different anion([TMGH][Im]and[TMGH][PhO])on the CO_(2)separation performance of the prepared ILs/Pebax blended membranes were systematically investigated at different temperature.The results showed the CO_(2)permeability exhibits the rising trend for ILs/Pebax blended membranes with the increment of IL content.Especially,the[TMGH][Im]with low viscosity and high CO_(2)absorption capacity leads to the blended membranes showing better CO_(2)permeability and ideal CO_(2)selectivity than that of membranes with[TMGH][PhO]at high IL content.Besides,with operating temperature increasing,the gas permeability of 20%(mass)[TMGH][Im]/Pebax blended membrane increases due to the decreasing viscosity of IL and the rising chain mobility of polymer.Inversely,the gas selectivity shows decreasing trend because CO_(2)absorption capacity obviously decreased at higher temperature.
基金
supported by the National Key R&D Program of China(2020YFA0710200)
the Science Fund for Creative Research Groups of the National Natural Science Foundation of China(21921005)
the Major Scientific and Technological Project of Shanxi Province of China(20201102005)
the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2020047)
the Innovation Academy for Green Manufacture,Chinese Academy of Sciences(IAGM2020C15)。
