多齿羧酸配体与锕系元素的自组装研究进展

Progress in Self-Assembly of Polycarboxylic Acid Ligands With Actinides

锕系元素的自组装是化学材料研究领域中的研究热点之一,其中锕系金属有机骨架材料(actinide metal organic frameworks, An-MOF)由于具备结构可调控、配位模式丰富以及功能多样性等优势而受到广泛关注,近年来在该方面取得了一系列重要进展。本文首先对国内外在An-MOF的合成和性能研究方面取得的进展进行简要综述,其次分别对本课题组在含铀和含钍两类金属有机骨架材料构筑方面的工作进行系统介绍,最后展望了锕系元素自组装的未来发展方向。

The self-assembly of actinides represents a cutting-edge research topic in the field of chemical materials, among which the actinide metal organic frameworks(An-MOF) emerge as the most shining star due to their tailorable structure, abundant coordination modes and versatile functionality, and have gained significant progress in recent years. In this review, the domestic and foreign advances of the synthesis and property investigation of An-MOF are first summary. Then a systematic introduction of uranium-and thorium-MOFs developed in our group is presented. Finally, the future direction of actinide self-assembly chemistry is briefly prospected.