摘要
The microscopic Bouligand-type architectures of fish scales demonstrate a notable efficiency in enhancing the damage tolerance of materials;nevertheless,it is challenging to reproduce in metals.Here bioinspired tungsten-copper composites with different Bouligand-type architectures mimicking fish scales were fabricated by infiltrating a copper melt into woven contextures of tungsten fibers.These composites exhibit a synergetic enhancement in both strength and ductility at room temperature along with an improved resistance to high-temperature oxidization.The strengths were interpreted by adapting the classical laminate theory to incorporate the characteristics of Bouligand-type architectures.In particular,under load the tungsten fibers can reorient adaptively within the copper matrix by their straightening,stretching,interfacial sliding with the matrix,and the cooperative kinking deformation of fiber grids,representing a successful implementation of the optimizing mechanisms of the Bouligand-type architectures to enhance strength and toughness.This study may serve to promote the development of new high-performance tungsten-copper composites for applications,e.g.,as electrical contacts or heat sinks,and offer a viable approach for constructing bioinspired architectures in metallic materials.
基金
the financial support by the National Key R&D Program of China under grant number 2020YFA0710404
the National Natural Science Foundation of China under grant number 51871216
the KC Wong Education Foundation(GJTD-2020-09)
the Liao Ning Revitalization Talents Program
the State Key Laboratory for Modification of Chemical Fibers and Polymer Materials at Donghua University
the Opening Project of Jiangsu Province Key Laboratory of High-End Structural Materials under grant number hsm1801
the Youth Innovation Promotion Association CAS
support from the Multidisciplinary University Research Initiative to University of California Riverside,funded by the Air Force Office of Scientific Research(AFOSR-FA9550–15–1–0009)and subcontracted to the University of California Berkeley。