摘要
The utilization of 2,6-bis(imidazo[1,5-a]pyridin-3-yl)pyridine(bipp)and 3-(pyridin-2-yl)imidazo[1,5-a]pyridine(pip)in the compounds of manganese(Ⅱ)and copper(Ⅰ)ions is presented.Two complexes,[Mn(bipp)(SO_(4))(H_(2)O)]n(1)and[Cu(pip)_(2)]ClO_(4)(2),were prepared with different characteristics in structure.Compound 1 exhibits a one-dimensional chain topology,and 2 is a homoleptic Cu(Ⅰ)complex.The dc magnetic susceptibility investigations reveal the antiferromagnetic(AF)MnⅡ···MnⅡinteractions in complex 1.The catalytic activity of compound 2 toward ketalization reactions was studied.Complex 2 exhibits high activity for the ketalization transformations of aliphatic ketones.
作者
张茜
崔燕峰
张夏梅
李亚红
姚金雷
ZHANG Qian;CUI Yan-Feng;ZHANG Xia-Mei;LI Ya-Hong;YAO Jin-Lei(College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China;Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application,School of Physical Science and Technology,Suzhou University of Science and Technology,Suzhou 215009,China)
基金
supported by the National Natural Science Foundation of China (21772140, 21771136)
Natural Science Foundation of Jiangsu Province (BK20171213)
the Priority Academic Program Development of Jiangsu Higher Education Institution
the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)
