金属有机框架基衍生物光催化析氢的研究进展

Advances in Photocatalytic Hydrogen Evolution of Metal-organic Framework Derivatives

通过光催化水,生产清洁、可持续的氢燃料,是实现更高的可持续性发展的理想策略。近年来,金属有机骨架(MOF)因具有超高孔隙率/高表面积的可达活性位点,作为衍生光催化剂,在光催化析氢方面得到了发展。本文简单论述了MOF衍生氧化物、硫化物、磷化物作为光催化剂产生H_(2)的研究进展,以期为设计和开发高效的MOF基衍生物光催化剂提供帮助,使其在光催化方面的研究迈向一个新的水平。

The production of clean and sustainable hydrogen fuel through photocatalytic water was an ideal strategy for achieving higher sustainability.In recent years,metal-organic frameworks(MOF)was developed in the field of photocatalytic hydrogen evolution due to their ultra-high porosity/high surface area reachable active sites.This paper briefly discussed the research progress of MOF-derived oxides,sulfides and phosphating compounds as photocatalysts for H_(2) generation,in order to provide help for the design and development of efficient MOF based derivative photocatalysts and made their research in photocatalysis to a new level.