摘要
共价有机框架材料(COFs)是一种新颖的多孔聚合物,有机构建单元通过较强的共价键准确连接以形成具有周期性的多孔框架结构。COFs具有高效、高选择性及高稳定性等特点,常作为催化剂的载体应用于不同领域,未来在多相催化加氢中具有更广泛的应用前景。主要综述了COFs的分类、合成方法及其在多相催化加氢反应中的应用与优势,并对其发展趋势进行了展望,以便寻找更适合COFs的发展方向。
Covalent organic frameworks(COFs)are a kind of novel porous polymer materials that the periodic organic building units can be precisely constructed via strong covalent bonds.Due to their high efficiency,high selectivity and high stability,they are often used as catalyst carriers in different fields,and they will have widespread application prospects in heterogeneous catalytic hydrogenation in the future.Here,it mainly reviews the classification of COFs and synthesis strategies,analyzes merits and disadvantages of COFs in heterogeneously catalytic hydrogenation reactions,and also gives the prospects and summary of the COFs catalysts,contributing to find the future directions for COFs.
作者
邓鑫
张思凡
许钧圆
陈秉辉
李立清
朱丽华
Deng Xin;Zhang Sifan;Xu Junyuan;Chen Binghui;Li Liqing;Zhu Lihua(College of Chemistry and Chemical Engineering,Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou Jiangxi 341000,China;College of Chemistry and Chemical Engineering,Xiamen University,Xiamen Fujian 361005,China)
出处
《石油化工》
CAS
CSCD
北大核心
2022年第4期467-476,共10页
Petrochemical Technology
基金
国家自然科学基金项目(21763011,22162012)
江西省杰出青年人才培养计划(20192BCB23015)
江西省青年井冈学者项目([2019]57)
2020年赣州市创新人才项目
中国博士后科学基金项目(2018M642597)
2019年江西省博士后基金项目
江西理工大学清江拔尖人才计划项目(JXUSTQJYX2017006)。
关键词
共价有机框架材料
催化剂
多相催化加氢
covalent organic framework materials
catalysts
heterogeneous catalytic hydrogenation