摘要
By intergranular addition of Pr-Cu-Ti alloy powders in the Nd-Fe-B sintered magnets with the normal B component,we propose an approach to the optimization of grain boundary and local Nd-Fe-B composition system.The coercivity is enhanced from 1.42 to 1.86 T,while further addition leads to a reduction in remanence and coercivity.The analyses of phase composition reveal that Ti mainly exists in the form of metallic Ti alloy,and part of Ti combines with B to form the TiB2 phase after the liquid phase sintering process.This process results in a consumption of B in the local Nd-Fe-B composition system and a change of the grain boundary component,which contributes to the formation process of the RE_(6)(Fe,M)_(14) phase after the annealing process.Therefore,with the modification of grain boundary and composition system,the intergranular addition of Pr-Cu-Ti induces the generation of continuous thin grain boundary phases.It promotes the intergrain exchange decoupling,increasing the coercivity in the annealed magnet.While the excess addition results in the segregation of TiB_(2),as well as the precipitation of TiB_(2) into the Nd-Fe-B phase,which leads to structural defects.Thus,the further effort for the addition alloy with Ti to reduce the deterioration of the microstructure will lead to further improvement in magnetic properties.
基金
Project supported by Major Project of"Science and Technology Innovation 2025"in Ningbo(2018B10086)
Major project of"Inner Mongolia Science and Technology"(2019ZD020)
Zhejiang Province Public Welfare Technology Application Research Project(LGG21E010007)
Major Scientific and Technological Re search and Development Projects in Jiangxi Province(20203ABC28W006)
Kunpeng Project in Zhejiang Province,National Natural Science Foundation of China(52101238)
Ningbo Top Talent Program。
