摘要
采用萃取法从电解锰净化渣浸出液中回收锰、钴、镍。试验结果表明:在P204皂化率60%、水相pH=4.0、萃取时间15 min、相比1:2条件下、锰的萃取率可达到90.3%;在P507皂化率60%、水相pH=5、萃取时间15 min,相比=1:3条件下,钴萃取率可达88.9%,最终试验锰、钴、镍回收率分别为90.3%、81.0%和80.5%;在N_( Ca+Mg):N_( F)=1:1.5、80℃、搅拌反应1 h条件下,浸出液钙镁含量分别为1.5 mg/L和2.0 mg/L;实现了有价金属分离回收。
Manganese,cobalt and nickel were recovered from the leaching solution of electrolytic manganese purification residue by extraction.The results showed that the extraction rate of manganese can reach 90.3%under the conditions of 60%saponification rate of P204,aqueous pH=4.0,extraction time of 15 min and ratio of 1:2,under the conditions of P507 saponification rate of 60%,aqueous pH=5,extraction time of 15 min and ratio=1:3,the extraction rate of cobalt can reach 88.9%,and the recoveries of manganese,cobalt and nickel were 90.3%,81.0%and 80.5%respectively,under the conditions of_( NCA+Mg):N_(F)=1:1.5,80℃and stirring reaction for 1 h,the contents of calcium and magnesium in the leaching solution were 1.5 mg/L and 2.0 mg/L respectively.The separation and recovery of valuable metals were realized.
作者
黎桂昌
吴元花
叶有明
谢雪珍
文美娜
LI Gui-chang;WU Yuan-hua;YE You-ming;XIE Xue-zhen;WEN Mei-na(Guangxi Science&Technology,Normal University,Guangxi Laibin 546199;Guangxi Guiliu New Material Co.,Ltd.,Guangxi Liuzhou 545004,China)
出处
《广州化工》
CAS
2022年第13期55-58,75,共5页
GuangZhou Chemical Industry
基金
2019年广西大学生创新创业训练项目(No:201911546032)
广西无机材料绿色制备与应用重点实验室
柳州市科技计划项目(No:2019BG10601)。
关键词
浸出液
萃取
锰
钴
镍
leaching solution
extraction
manganese
cobalt
nickel