摘要
SO_(2)与N,N-二烯丙基胺共聚物具有聚砜及胺基聚合物的结构,在添加剂、凝聚剂、增稠剂、催化剂和杀菌剂等方面有重要的研究价值和广阔的应用前景。对SO_(2)与N,N-二烯丙基胺盐通过Butler环化共聚机理制备新型材料及其产物性能、应用领域进行了系统综述,通过与不同N,N-二烯丙基胺盐的环化共聚产物性能及应用领域进行对比,进一步分析了聚合物主链上SO_(2)的嵌入对聚合效率及性能的影响规律,为今后SO_(2)共聚领域的发展提供指导和帮助。
Copolymers of N,N-diallylamine and SO_(2) have some special structures of polysulfone and ammonium polymer,which have been applied in additive,coagulating agent,thickening agent,catalyst,fungicides and so on.Copolymerization of N,N-diallylamine and SO_(2) has an important research value and broad application prospects.This paper summarized the copolymerization of N,N-diallylamine and SO_(2) by Butler′s cyclopolymerization mechanism in recent years.By comparing with the performances of the cyclopolymers with the different structures,the effects of SO_(2) on polymerization efficiency and performance were further analyzed.We wish this review could be helpful and guided to SO_(2) copolymerization.
作者
王丽媛
李珍
刘毅
支云飞
陕绍云
苏红莹
WANG Liyuan;LI Zhen;LIU Yi;ZHI Yunfei;SHAN Shaoyun;SU Hongying(Tin Chemical Company Limited of Yunnan Tin Co. Ltd.,Gejiu 661000,China;Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650504,China)
出处
《化工科技》
CAS
2022年第2期77-82,共6页
Science & Technology in Chemical Industry
基金
国家自然科学基金项目(21766016,22068023)
云南省“万人计划”基金项目(YNWR-QNBJ-2018-198)
昆明市科学技术局科技计划基金项目(2019-1-G-25318000003480)。